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OCCURRENCE OF EMERGING ORGANIC CHEMICALS IN WASTEWATER EFFLUENTS FROM ONSITE SYSTEMS
Published by the American Society of Agricultural and Biological Engineers, St. Joseph, Michigan www.asabe.org
Citation: Paper number 701P0104, .
Authors: K.E. DeJong, R.L. Siegrist, L.B. Barber, A.L. Wren
Keywords: Septic Tanks, Trace Organic Compounds, Wastewater Treatment, Water Quality Monitoring
Emerging organic chemicals (EOCs) have received increasing attention in the last decade due to
their possible adverse affects on ecosystems and human health. Several studies have suggested
wastewater as a primary contributing source of EOCs to the water environment, but few have
quantified their occurrence, especially in onsite wastewater treatment systems and associated
receiving environments. In Colorado there are over 600,000 onsite wastewater systems (OWS)
in operation, resulting in over 100 billion liters of wastewater that is being processed by OWS
and then discharged to the environment each year. The focus of the research described in this
paper is to determine the occurrence of a select group of EOCs in OWS and their receiving
environments. Thirty OWS, 11 groundwater wells, and 9 surface waters for a total of 50 sites in
the Colorado Rocky Mountain region are being analyzed for a suite of EOCs and wastewater
indicator compounds using two methods: (1) continuous liquid-liquid extraction with methylene
chloride, and (2) evaporation followed by derivatization to form propyl esters. Preliminary
results from analyses of samples collected from twelve of the selected sites have identified 10
compounds, including ethylenediaminetetraacetic acid, nitrilotriacetic acid, and
nonylphenolpolyethoxylates. Five EOCs were identified in OWS effluents: 4-nonylphenol (510-
28,000 ng/L), caffeine (5,300 – 11,000 ng/L), triclosan (14-130 ng/L), 3-â-coprostanol (1,100-
99,000 ng/L), and cholesterol (2,800-38,000 ng/L). The samples from each of the 50 sites have
been characterized with respect to general water and wastewater parameters and are presently
being analyzed for the suite of EOCs and wastewater indicator compounds. The results will aid
in defining the potential risks to ecosystems or human health due to EOCs discharged in OWS
effluents.
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