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KINETICS OF AMMONIA REMOVAL IN A PILOT-SCALE BIOFILTER
Published by the American Society of Agricultural and Biological Engineers, St. Joseph, Michigan www.asabe.org
Citation: Transactions of the ASAE. Vol. 47(5): 1867-1878 . @2004
Authors: J. R. Kastner, K. C. Das, B. Crompton
Keywords: Biofilter, Kinetics, Ammonia, Reactor design, Residence time distribution
A mobile, skid-mounted biofilter was designed and built to determine the kinetics of ammonia oxidation at a modern
2400-sow farrow-to-wean unit. The biofilter system consisted of a variable-speed blower, packed-bed humidifier, and
two reactors (packing volume of 0.35 m3 per reactor) configured in parallel. Prescreened, composted yard waste was used
since compost contains a large number of active microorganisms, is relatively inexpensive, and is readily available. Ammonia
emissions (0 to 12 ppmv or 0 to 8.4 mg m-3) from the swine facility (and 0 to 25 ppmv or 0 to 17.4 mg m-3 in a simulated stream)
were transported downward across the packing in the reactors, and spray nozzles at the top of each reactor were used to add
moisture to the packing. Ammonia removal ranged from 25% to 95% depending on the residence time and inlet NH3
concentration. Using first-order kinetics, the measured ammonia degradation rate ranged from 0.06 to 0.80 mg NH3 m-3 s-1
for volumetric loading rates ranging from 0.05 to 0.25 mg NH3 m-3 s-1. Residence time distribution (RTD) analysis was also
performed to determine the effect of scale-up on axial dispersion and deviation from plug flow. RTD analyses suggest that
non-ideal reactor design equations may be required to predict reactor size for desired ammonia conversions. A reactor design
method (i.e., sizing calculation) was developed based on the kinetics of ammonia oxidation. For example, assuming a
volumetric flow rate of 13 m3 s-1, NH3 conversion of 95% (CNH3in = 25 ppmv), and a first-order rate constant of 0.08 s-1,
a reactor volume of 487 m3 and residence time of 37.5 s is required. The size of the reactor will change depending on the
characteristics of the swine facility. Pressure drops across the bed should be 50 Pa or less in order to utilize in-house fans.
This will probably limit the height of the reactor to 1 m or less. The mass of compost required can be estimated from its bulk
density. Moisture content must be maintained between 40% and 60% in the biofilter to maintain biological activity. Additional
research is required to develop inexpensive methods of emission humidification, online moisture analysis, and water addition.
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